Ammonium citrate dibasic CAS NO.3012-65-5
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- Available Specifications:
99(1-10)Metric Ton
- Product Details
Keywords
- 1,2,3-Propanetricarboxylicacid, 2-hydroxy-, diammonium salt (9CI)
- Citric acid, diammonium salt (8CI)
- AmmCitrate
Quick Details
- ProName: Low Price Ammonium citrate dibasic
- CasNo: 3012-65-5
- Molecular Formula: C6H8O7·2H3N
- Appearance: White powder
- Application: Analytical reagents, such as compound ...
- DeliveryTime: 3-5DAYS
- PackAge: 25KG/BAG OT ACCORDING TO CUSTOMER REQU...
- Port: ANY PORT IN CHINA
- ProductionCapacity: 100000 Metric Ton/Month
- Purity: 99
- Storage: Dry and cool warehouse
- Transportation: BY SEA OR AIR
- LimitNum: 1
- pH (50g/L solution,25℃): 4.5-5.5
- Sulfur compound(as SO4),w/% ≤: 0.005
Superiority
1.Chemical name: diammonium hydrogen citrate, diammonium hydrogen citrate
2.Molecular formula: C6H14N2O7
3.Molecular weight: 226.192
4. CAS: 3012-65-5
5, Performance: colorless fine crystals or white particles. Density is 1.48g/mL, melting point 185 ºC, boiling point 100ºC, soluble in water, slightly soluble in ethanol.
6. Use: analytical reagents, such as extraction agent, masking agent, buffer agent.
7, Packaging: lined with polyethylene plastic bag, coat composite plastic woven bag packaging, each bag net weight 25kg.
8, Storage and transportation: This product should be stored in a dry, ventilated and clean warehouse, loading and transportation should be light, to prevent packaging damage, to prevent moisture, heat, rain during transportation to prevent moisture, should be isolated from toxic substances.
Item | FCC VII |
Content (On dry basis),w/% ≥ | 98% |
Chloride (Cl),mg/kg ≤ | 10 |
Iron (Fe),mg/kg ≤ | 10 |
Lead (Pb),mg/kg ≤ | 2 |
pH (50g/L solution,25℃) | 4.5-5.5 |
Water insoluble,w/% ≤ | / |
Ignition Residue (as SO4),w/% ≤ | / |
Sulfur compound(as SO4),w/% ≤ | 0.005 |
Phosphorus compound(as PO4),w/%≤ | PASS |
Oxalate(C2O4),w/% ≤ | PASS |
Calcium (Ca),w/% ≤ | PASS |
Clarity test | PASS |
SAFETY DATA SHEETS
According to the UN GHS revision 10
Version: 1.0
Creation Date: July 15, 2019
Revision Date: July 15, 2019
SECTION 1: Identification
1.1GHS Product identifier
Product name |
Diammonium hydrogen 2-hydroxypropane-1,2,3-tricarboxylate |
---|
1.2Other means of identification
Product number |
- |
---|---|
Other names |
diammoniumcitrate; Ammonium citrate dibasic; Citronensaeure,Diammonium-Salz |
1.3Recommended use of the chemical and restrictions on use
Identified uses |
Industrial and scientific research use. |
---|---|
Uses advised against |
no data available |
SECTION 2: Hazard identification
2.1Classification of the substance or mixture
Skin irritation, Category 2
Eye irritation, Category 2
2.2GHS label elements, including precautionary statements
Pictogram(s) | |
---|---|
Signal word |
Warning |
Hazard statement(s) |
H315 Causes skin irritation H319 Causes serious eye irritation |
Precautionary statement(s) | |
Prevention |
P264 Wash ... thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/... |
Response |
P302+P352 IF ON SKIN: Wash with plenty of water/... P321 Specific treatment (see ... on this label). P332+P317 If skin irritation occurs: Get medical help. P362+P364 Take off contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
Storage |
none |
Disposal |
none |
2.3Other hazards which do not result in classification
no data available
SECTION 3: Composition/information on ingredients
3.1Substances
Chemical name | Common names and synonyms | CAS number | EC number | Concentration |
---|---|---|---|---|
Diammonium hydrogen 2-hydroxypropane-1,2,3-tricarboxylate | Diammonium hydrogen 2-hydroxypropane-1,2,3-tricarboxylate | 3012-65-5 | 221-146-3 | 100% |
SECTION 4: First-aid measures
4.1Description of necessary first-aid measures
If inhaled
Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.
Following skin contact
Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.
Following eye contact
Rinse with pure water for at least 15 minutes. Consult a doctor.
Following ingestion
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
4.2Most important symptoms/effects, acute and delayed
Inhalation causes respiratory irritation. Ingestion causes diarrhea. Contact with eyes causes mild irritation. (USCG, 1999)
4.3Indication of immediate medical attention and special treatment needed, if necessary
Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for signs of pulmonary edema and treat if necessary . Monitor for shock and treat if necessary . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during transport . Do not use emetics. For ingestion, rinse mouth and administer 5 mg/kg up to 200 ml of water for dilution if the patent can swallow, has a strong gag reflex, and does not drool . Do not attempt to neutralize. Ammonia and related compounds
SECTION 5: Fire-fighting measures
5.1Suitable extinguishing media
Extinguish fire using agent suitable for type of surrounding fire. (Material itself does not burn or burns with difficulty.) Ammonium chloride
5.2Specific hazards arising from the chemical
Special Hazards of Combustion Products: Toxic ammonia gas may form in fire. (USCG, 1999)
5.3Special protective actions for fire-fighters
Wear self-contained breathing apparatus for firefighting if necessary.
SECTION 6: Accidental release measures
6.1Personal precautions, protective equipment and emergency procedures
Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak.
6.2Environmental precautions
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
6.3Methods and materials for containment and cleaning up
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
SECTION 7: Handling and storage
7.1Precautions for safe handling
Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
7.2Conditions for safe storage, including any incompatibilities
Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.
SECTION 8: Exposure controls/personal protection
8.1Control parameters
Occupational Exposure limit values
no data available
Biological limit values
no data available
8.2Appropriate engineering controls
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
8.3Individual protection measures, such as personal protective equipment (PPE)
Eye/face protection
Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US).
Skin protection
Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Respiratory protection
If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator.
Thermal hazards
no data available
SECTION 9: Physical and chemical properties and safety characteristics
Physical state |
Ammonium citrate is a white granular solid. It is soluble in water. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. It is used in pharmaceuticals, and in chemical analysis. |
---|---|
Colour |
Granules or crystals |
Odour |
Slight ammoniacal |
Melting point/freezing point |
185 °C (dec.)(lit.) |
Boiling point or initial boiling point and boiling range |
100 °C(lit.) |
Flammability |
no data available |
Lower and upper explosion limit/flammability limit |
no data available |
Flash point |
155.2°C |
Auto-ignition temperature |
no data available |
Decomposition temperature |
no data available |
pH |
pH = 4.3 (0.1 molar soln in water) |
Kinematic viscosity |
no data available |
Solubility |
Slightly soluble in alcohol |
Partition coefficient n-octanol/water |
no data available |
Vapour pressure |
no data available |
Density and/or relative density |
1.5 |
Relative vapour density |
1.8 (vs air) |
Particle characteristics |
no data available |
SECTION 10: Stability and reactivity
10.1Reactivity
no data available
10.2Chemical stability
no data available
10.3Possibility of hazardous reactions
Acidic salts, such as AMMONIUM CITRATE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.
10.4Conditions to avoid
no data available
10.5Incompatible materials
no data available
10.6Hazardous decomposition products
Toxic ammonia gas may form in fire.
SECTION 11: Toxicological information
Acute toxicity
- Oral: no data available
- Inhalation: no data available
- Dermal: no data available
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
STOT-single exposure
no data available
STOT-repeated exposure
no data available
Aspiration hazard
no data available
SECTION 12: Ecological information
12.1Toxicity
- Toxicity to fish: no data available
- Toxicity to daphnia and other aquatic invertebrates: no data available
- Toxicity to algae: no data available
- Toxicity to microorganisms: no data available
12.2Persistence and degradability
no data available
12.3Bioaccumulative potential
no data available
12.4Mobility in soil
no data available
12.5Other adverse effects
no data available
SECTION 13: Disposal considerations
13.1Disposal methods
Product
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packaging
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
SECTION 14: Transport information
14.1UN Number
ADR/RID: Not dangerous goods. (For reference only, please check.) | IMDG: Not dangerous goods. (For reference only, please check.) | IATA: Not dangerous goods. (For reference only, please check.) |
14.2UN Proper Shipping Name
ADR/RID: Not dangerous goods. (For reference only, please check.) | IMDG: Not dangerous goods. (For reference only, please check.) | IATA: Not dangerous goods. (For reference only, please check.) |
14.3Transport hazard class(es)
ADR/RID: Not dangerous goods. (For reference only, please check.) | IMDG: Not dangerous goods. (For reference only, please check.) | IATA: Not dangerous goods. (For reference only, please check.) |
14.4Packing group, if applicable
ADR/RID: Not dangerous goods. (For reference only, please check.) | IMDG: Not dangerous goods. (For reference only, please check.) | IATA: Not dangerous goods. (For reference only, please check.) |
14.5Environmental hazards
ADR/RID: No | IMDG: No | IATA: No |
14.6Special precautions for user
no data available
14.7Transport in bulk according to IMO instruments
no data available
SECTION 15: Regulatory information
15.1Safety, health and environmental regulations specific for the product in question
Chemical name | Common names and synonyms | CAS number | EC number |
---|---|---|---|
Diammonium hydrogen 2-hydroxypropane-1,2,3-tricarboxylate | Diammonium hydrogen 2-hydroxypropane-1,2,3-tricarboxylate | 3012-65-5 | 221-146-3 |
European Inventory of Existing Commercial Chemical Substances (EINECS) | Listed. | ||
EC Inventory | Listed. | ||
United States Toxic Substances Control Act (TSCA) Inventory | Listed. | ||
China Catalog of Hazardous chemicals 2015 | Not Listed. | ||
New Zealand Inventory of Chemicals (NZIoC) | Listed. | ||
Philippines Inventory of Chemicals and Chemical Substances (PICCS) | Listed. | ||
Vietnam National Chemical Inventory | Listed. | ||
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) | Listed. | ||
Korea Existing Chemicals List (KECL) | Listed. |
SECTION 16: Other information
Information on revision
Creation Date | July 15, 2019 |
---|---|
Revision Date | July 15, 2019 |
Abbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
Package&Shipping
Details
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