Lowder Price DODECYL BENZENESULFONIC ACID(LABSA 96%) CAS NO.27176-87-0
- FOB Price: USD: /Metric Ton Get Latest Price
- Min.Order: 1 Metric Ton
- Payment Terms: L/C,D/A,D/P,T/T,Other
- Available Specifications:
96%(1-10)Metric Ton
- Product Details
Keywords
- A 40S
- ABS100
- LABSA
Quick Details
- ProName: Dodecylbenzenesulfonic Acid(LABSA 96%)
- CasNo: 27176-87-0
- Molecular Formula: C18H30O3S
- Appearance: Brown viscous liquid
- Application: Detergent raw material
- DeliveryTime: 3-5days
- PackAge: 200kg/drum
- Port: Any port in China
- ProductionCapacity: 100000 Metric Ton/Month
- Purity: 96
- Storage: Cool and dry place, avoid sun and rain
- Transportation: By sea or air
- LimitNum: 1 Metric Ton
- APHA color Pt-Co Scale: 18
- Grade: Industrial Grade
- SULFURIC ACID %: 1.5 Max
- FREE OIL %: 2.0 Max
Superiority
Safety Data Sheet
1. Identification of substance
Product Name: DODECYL BENZENESULFONIC ACID
Other Name: None
Chemical Name: None
Recommended Use: WIDELY USED IN SHAMPOO, BATH LIQUID, TABLEWARE DETERGENT, COMPOUND SOAP, SUCH AS WASHING COSMETIC SUPPLIES;USED AS WETTING AGENT AND CLEANER IN TEXTILE INDUSTRY.
2. Hazards identification
GHS classification: Corrosive to metals 1 Acute toxicity-oral 4 Skin corrosion/irritation 1B Serious eye damage/eye irritation 1
Signal words Danger
Hazard statements H290:May be corrosive to metals
H302:Harmful if swallowed
H314:Causes severe skin burns and eye damage
H318:Causes serious eye damage
Precautionary Statement Prevention
P234:Keep only in original packaging.
P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264+P265:Wash hands [and…] thoroughly after handing.
Do not touch eyes.
P270:Do not eat, drink or smoke when using this product.
P280:Wear protective gloves/protective clothing/eye
protection/face protection/hearing protection.
Precautionary Statement Response
P301+P317:IF SWALLOWED: Get medical help.
P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P361+P354:IF ON SKIN: Take off immediately all contaminated clothing. Immediately rinse with water for several minutes.
P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P354+P338:IF IN EYES:Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P316:Get emergency medical help immediately.
P317:Get medical help.
P321:Specific treatment (see the supplemental first aid instruction).
P330:Rinse mouth.
P363:Wash contaminated clothing before reuse
P390:Absorb spillage to prevent material damage.
Precautionary Statement Storage
P405:Store locked up.
P406:Store in corrosive resistant/…container with a resistant inner liner.
Precautionary Statement Disposal
P501:Dispose of contents/container in according with local regulation.
Other hazards which do not result in classification
Not available.
3. Composition/information on ingredients
□Substances
√Mixtures
Component Information
Component CAS number EINECS number Mass(%)
Linear Alkylbenzene 27176-87-0 248-289-4 ≥96%wt
Sulfonic Acid
Linear Alkylbenzene 123-01-3 204-591-8 ≤2%wt
Sulfuric acid 7664-93-9 231-639-5 ≤1.5%wt
Note:1. Unless a component presents a severe hazard, it does not need to be considered in the SDS if the concentration is less than 1%.
4.First-aid measures
NOTE TO PHYSICIAN
In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation.
After inhalation
Move to fresh air. Oxygen or artificial respiration if needed. Get immediate medical attention.
After skin contact
Immediately flush skin with plenty of water. Remove and isolate contaminated clothing and shoes. If irritation persists, get medical attention immediately. For minor skin contact, avoid spreading material on unaffected skin.
Wash clothing separately before reuse.
After eye contact
Immediately flush eyes with plenty of water for at least 15 minutes. Assure adequate flushing of the eyes by separating the eyelids with fingers. Get medical attention immediately.
After ingestion
Rinse mouth. Give one or two glasses of water to drink. Do not induce vomiting without medical advice. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Loosen tight clothing such as a collar, tie, belt or waistband. Do not use mouth-to-mouth method if victim ingested the substance. Seek immediate medical attention.
Most important symptoms/effects,acute and delayed
Cough, sore throat, difficulty breathing, redness, burns, burning sensation, shock, or collapse; Harmful if swallowed
Causes severe skin burns and eye damage
5. Fire-fighting measures
Suitable extinguishing agents
Dry chemical powder, water spray, carbon dioxide or alcohol-resistant foam.
Special hazards caused by the material, its products of combustion or flue gases
Decomposes above 205 °C. This produces toxic fumes including sulfur oxides and hydrogen sulfide. Reacts with bases and oxidants. This produces sulfur oxides. This generates toxic hazard. Attacks metals.
Protective equipment for fire-fighters
Firefighters should wear air breathing apparatus, full body fire-fighting clothing and oil resistant rubber gloves, and put out the fire at a safe distance and with sufficient protection.
Move the container from the fire to the open space as far as possible. Evacuate immediately if containers in the fire field are discolourable or sound from the safety relief device.
Isolate the scene of the accident and prohibit irrelevant
personnel from entering. Collect and treat fire water to prevent environmental pollution.
6. Accidental release measures
Person-related safety precautions
Remove all sources of ignition. Isolate accident scene, set warning signs around, and evacuate irrelevant personnel to the safety area from crosswind and upwind.
It is suggested that the safety treatment personnel should wear positive pressure self-contained breathing apparatus, chemical protective clothing and chemical protective gloves. Direct contact with leakage is prohibited. Prevent contact with skin and eyes. Cut off the leakage source as much as possible.
Measures for environmental protection
Prevent further leakage or spillage if safe to do so. Do not allow material to be released to the environment without proper governmental permits.
Measures for cleaning/collecting
Small amount of leakage: collect in dry, clean and covered container with clean shovel, and transfer to a safe place. Do not flush into the sewer.
Large amount of leakage: build a causeway or trenching asylum. Close the drain pipe. Cover with foam, inhibit evaporation. Transfer to tank car or special collector with explosion-proof pump, recycle or transport to waste treatment site for disposal.
Additional information
See Section 7 for information on safe handling.
See section 8 for information on personal protection equipment.
See Section 13 for information on disposal.
7. Handling and storage
Handling
Information for safe handling
Airtight operation, provide adequate local exhaust.
Operators must be specially trained and strictly abide by the operation rules. It is suggested that the operators should wear self-contained filter gas mask, safety glasses, impervious work clothes and chemical resistant gloves. Keep
away from fire and heat sources. Smoking is forbidden in the workplace. Handle with care to prevent damage to packaging and containers. Equip with corresponding varieties and quantities of fire fighting equipment and leakage emergency equipment. Empty containers may contain harmful substances.
Information about
protection against
explosions and fires
Cut off the leakage source as far as possible and eliminate all ignition sources.
STORAGE
Requirements to be met by storerooms and containers
Store in a cool and well-ventilated warehouse. Store separately from reducing agents, perchlorates, nitrates, metal powders, oxidizing agents, nitric acids and bases and avoid mixed storage. Keep tightly closed until used. Keep away from fire and heat source.
Information about storage in one common storage facility
Stay away from incompatible substances such as Reducing agents,perchlorates, nitrates, metal powders, oxidizing agents, nitric acids and bases. Emergency handling equipment and suitable receiving materials should be provided in the storage area.
Store locked up.
Further information about storage conditions
No data.
8. Exposure controls/personal protection
Limit Values for Exposure
Component
CAS | ACGIH TLV-TWA | ACGIH TLV-STEL | NIOSH PEL-TWA | NIOSH PEL-STEL | |
Linear Alkylbenzene | 27176-87- 0 | N.E. | N.E. | N.E. | N.E. |
Sulfonic Acid | 0 | ||||
Linear Alkylbenzene | 123-01-3 | N.E. | N.E. | N.E. | N.E. |
Sulfuric acid | 7664-93-9 | 0.2 mg/m3 | N.E. | 1 mg/m3 | N.E. |
Appropriate engineering controls
Workplace should be separated from other workplaces. Airtight operation to prevent leakage. Strengthen ventilation. Set up automatic alarm device and accident ventilation facilities. Set up emergency evacuation channel and necessary danger area. Set up red area warning line, warning sign and Chinese warning instruction, and set up communication alarm system. Provide safety shower and eye wash equipment.
General protective and hygienic measures
Do not get this material in contact with skin. Do not get this material on clothing. Avoid contact with eyes. Handle in accordance with good industrial hygiene and safety practice.
Wash hands before breaks and at the end of workday.
Personal protective equipment
Chemical safety glasses, gloves, protective clothing and a dust/vapor respirator or mask.
Breathing equipment
Use self-contained breathing apparatus in all cases.
Protection of hands
Wear appropriate chemical resistant gloves.
Eye/Face protection
Tightly sealed goggles.
Body protection
Full set of anti chemical reagent overalls, flame retardant
antistatic protective clothing, choose body protection
according to the amount and concentration of the dangerous
substance at the work place.
Note: 1. N.E. means not established.
9.Physical and chemical properties
Physical state Viscous liquid
Colour Brown
Odour No data available
Melting point/freezing point No data available
Boiling point or initial >100 ℃
boiling point and boiling
range
Flammability Nonflammable
Lower and upper explosion No data available
limit/ flammability limit >100 ℃ (Closed cup)
Flash point
Auto-ignition temperature No data available
Decomposition No data available
temperature
pH <1
Kinematic viscosity No data available
Solubility Soluble in water.
Partition coefficient: No data available
n-octanol/water(log value)
Vapour pressure No data available
Density and/or relative No data available
density
Relative vapour density 1.1
(air=1)
Particle characteristics Not applicable
10. Stability and reactivity
Reactivity
Decomposes above 205 °C. This produces toxic fumes including sulfur oxides and hydrogen sulfide. Reacts with bases and oxidants. This produces sulfur oxides. This generates toxic hazard. Attacks metals.
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
According to the instructions, it will not decompose.
Conditions to avoid (e.g. static discharge, shock or vibration)
Heat, flames and sparks, extreme temperatures and direct sunlight.
Incompatible materials
Reducing agents, perchlorates, nitrates, metal powders, oxidizing agents, nitric acids and bases.
Hazardous decomposition products
Carbon oxides, sulfur oxides and hydrogen sulfide.
11.Toxicological information
This product is a preparation for which no toxicological data exists. When available, toxicological data for the product’s hazardous ingredients are provided below.
Routes of Entry: Dermal contact, eye contact, inhalation, ingestion.
Acute Toxicity
Linear Alkylbenzene LD50 (Oral, rat): 650 mg/kg
Sulfonic Acid(CAS 27176-87-0) LC50 (Inhalation, rat): N/A
LD50 (Dermal, rabbit): N/A
Sulfuric acid(CAS 7664-93-9) LD50 (Oral, rat): 2140 mg/kg
LC50 (Inhalation, rat): 510 mg/m3 (2h)
LD50 (Dermal, rabbit): N/A
Skin corrosion/Irritation
Causes severe skin burns and eye damage.
Serious eye Causes serious eye damage.
damage/irritation
Respiratory or skin Not classified
sensitization
Germ cell mutagenicity Not classified
Carcinogenicity Not classified
Reproductive toxicity Not classified
STOT-single exposure Not classified
STOT-repeated exposure Not classified
Aspiration hazard Not classified
Chronic Effects Not classified
Further Information Not classified
12. Ecological information
Ecotoxicity
Aquatic Toxicity Sulfuric acid(CAS 7664-93-9)
Test & Species
96 Hr LC50 Fish: >500 mg/l
48 Hr EC50 Daphnia: N/A
72 Hr EC50 Algae: N/A
Persistence and Not available
degradability
Bioaccumulative potential Not available
Mobility in soil Not available
Additional Information Not available
13. Disposal considerations
WASTE DISPOSAL INSTRUCTIONS
Contact a qualified professional waste disposal service to dispose of this
material.
Dispose of in accordance with local environmental regulations or local
authority requirements.
14. Transport information
The Recommendation of Transport of Dangerous Goods(TDG)
UN Number UN 2586
Proper Shipping Name ALKYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid
Class/Division Class 8 Corrosive Substances
Package Group PG III
Subsidiary risk —
Maritime transport IMDG/ Being same with TDG/ No
Marine pollutant (Yes/No)
Air transport ICAO-TI and Being same with TDG
IATA-DGR See A803 for Special Provisions.
15. Regulatory information
European/International Regulations
OSHA: Hazardous by definition of Hazard Communication
Standard(29CFR 1910.1200).
EINECS Status: The main components of this chemical are included in EINECS inventory.
EPA TSCA Status: The main components of this chemical are included in TSCA inventory.
Canadian DSL(Domestic
Substances List):
The main components of this chemical are included in DSL.
HMIS(Hazardous Health: 3
Material Identification Flammability: 0
System Ratings): Physical hazard: 0
Personal protection: F
(4. Severe Hazard; 3. Serious Hazard; 2. Moderate Hazard; 1. Slight Hazard; 0. Minimal Hazard)
WHMIS(Canadian
E(Linear Alkylbenzene Sulfonic Acid),
Workplace Hazardous
D1A, E(Sulfuric acid)
Material Identification
System Ratings):
GB 12268-2012 List of
dangerous goods
This chemical is a dangerous goods on the GB 12268-2012
list of dangerous goods.
16. other information
Employers should use this information only as a supplement to other information
gathered by them, and should make independent judgment of suitability of this information
to ensure proper use and protect the health and safety of employees. This information is
furnished without warranty, and any use of the product not in conformance
with this Material Safety Data Sheet, or in combination with any other product or process,
is the responsibility of the user.
This Material Safety Data Sheet was based on the "Globally Harmonized System of
Classification and Labelling of Chemicals", "Recommendations on the TRANSPORT OF
DANGEROUS GOODS Model Regulations", "INTERNATIONAL MARITIME DANGEROUS
GOODS CODE"," International Air Transport Association Dangerous Goods Regulations",
the National Standards and other related dangerous chemicals management laws,
regulations and standards, which are periodically updated and changed. To make
dangerous goods / hazardous chemicals comply with the relevant requirements of the
latest management, regularly update is recommended.
This Material Safety Data Sheet has been compiled in both English and Chinese. For
any discrepancies, the Chinese version shall prevail.
Abbreviations and
acronyms
ADR: European Agreement concerning the International Carriage of
Dangerous Goods by Road
RID: Regulations Concerning the International Transport of
Dangerous Goods by Rail
IMDG: International Maritime Code for Dangerous Goods
IATA-DGR: Dangerous Goods Regulations by the "International Air Safety Data Sheet Page 9 of 9
DODECYL BENZENESULFONIC ACID According to GHS rev 9
Transport Association" (IATA)
ICAO-TI: Technical Instructions by the "International Civil Aviation
Organization" (ICAO)
EINECS: European Inventory of Existing Commercial Chemical
Substances
CAS: Chemical Abstracts Service
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
EC50: effective concentration,50 percent
Edit Date
02.06.2022
Update and Revise Second edition
Edit Standard
Globally Harmonized System of Classification and Labelling of
Chemicals Part 1.5
Package&Shipping
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