SAFETY DATA SHEETS

According to the UN GHS revision 9

Version: 1.0

Creation Date: July 15, 2019

Revision Date: July 15, 2019

SECTION 1: Identification

1.1GHS Product identifier

Product name	2-ethoxy-1-methylethyl acetate

1.2Other means of identification

Product number	-
Other names	EINECS 259-370-9; 1-ETHOXY-2-PROPYL ACETATE; 1,2-Propylene glycol ethyl ether acetate

1.3Recommended use of the chemical and restrictions on use

Identified uses	Industrial and scientific research use.
Uses advised against	no data available

1.4Supplier's details

Company	chemicalbook
Address	507, building 1, Huihuang international, Shangdi 10th Street, Haidian District, Beijing
Telephone	86-10-69703845

1.5Emergency phone number

Emergency phone number	13121892008
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

SECTION 2: Hazard identification

2.1Classification of the substance or mixture

Flammable liquids, Category 3

Specific target organ toxicity – single exposure, Category 3

2.2GHS label elements, including precautionary statements

Pictogram(s)
Signal word	Warning
Hazard statement(s)	H226 Flammable liquid and vapour H336 May cause drowsiness or dizziness
Precautionary statement(s)
Prevention	P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof [electrical/ventilating/lighting/...] equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/... P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area.
Response	P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse affected areas with water [or shower]. P370+P378 In case of fire: Use ... to extinguish. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P319 Get medical help if you feel unwell.
Storage	P403+P235 Store in a well-ventilated place. Keep cool. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.
Disposal	P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

2.3Other hazards which do not result in classification

no data available

SECTION 3: Composition/information on ingredients

3.1Substances

Chemical name	Common names and synonyms	CAS number	EC number	Concentration
2-ethoxy-1-methylethyl acetate	2-ethoxy-1-methylethyl acetate	54839-24-6	259-370-9	100%

SECTION 4: First-aid measures

4.1Description of necessary first-aid measures

If inhaled

Fresh air, rest.

Following skin contact

Remove contaminated clothes. Rinse skin with plenty of water or shower.

Following eye contact

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Following ingestion

Rinse mouth.

4.2Most important symptoms/effects, acute and delayed

no data available

4.3Indication of immediate medical attention and special treatment needed, if necessary

no data available

SECTION 5: Fire-fighting measures

5.1Suitable extinguishing media

Use water spray, powder, foam, carbon dioxide.

5.2Specific hazards arising from the chemical

Flammable. Above 53°C explosive vapour/air mixtures may be formed.

5.3Special protective actions for fire-fighters

Use water spray, powder, foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.

SECTION 6: Accidental release measures

6.1Personal precautions, protective equipment and emergency procedures

Remove all ignition sources. Ventilation. Collect leaking and spilled liquid in sealable containers as far as possible. Then wash away with plenty of water.

6.2Environmental precautions

Remove all ignition sources. Ventilation. Collect leaking and spilled liquid in sealable containers as far as possible. Then wash away with plenty of water.

6.3Methods and materials for containment and cleaning up

Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.

SECTION 7: Handling and storage

7.1Precautions for safe handling

NO open flames, NO sparks and NO smoking. Above 53°C use a closed system and ventilation. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

7.2Conditions for safe storage, including any incompatibilities

Fireproof.

SECTION 8: Exposure controls/personal protection

8.1Control parameters

Occupational Exposure limit values

MAK: 120 mg/m3, 20 ppm; peak limitation category: II(2); skin absorption (H); pregnancy risk group: C

Biological limit values

no data available

8.2Appropriate engineering controls

Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.

8.3Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Wear safety goggles.

Skin protection

Protective gloves.

Respiratory protection

Use ventilation, local exhaust or breathing protection.

Thermal hazards

no data available

SECTION 9: Physical and chemical properties and safety characteristics

Physical state	Liquid. Mobile liquid.
Colour	Colourless.
Odour	no data available
Melting point/freezing point	< -70 °C. Atm. press.:1 atm.
Boiling point or initial boiling point and boiling range	150 °C. Atm. press.:1 010 mBar. Remarks:Dry point 178.0 degrees C. Total volume recovered = 99.5 %.;148 °C. Atm. press.:1 010 mBar. Remarks:Dry point 179.2 degrees C. Total volume recovered = 99.5 %.
Flammability	Flammable.
Lower and upper explosion limit/flammability limit	no data available
Flash point	53 °C. Atm. press.:1 011 mBar.
Auto-ignition temperature	325 °C. Atm. press.:1 021 mBar.
Decomposition temperature	no data available
pH	no data available
Kinematic viscosity	kinematic viscosity (in mm²/s) = 2.173. Temperature:0.0°C.;kinematic viscosity (in mm²/s) = 1.691. Temperature:10.0°C.;kinematic viscosity (in mm²/s) = 1.411. Temperature:20°C.
Solubility	in water, g/100ml at 20°C: 9.5
Partition coefficient n-octanol/water	log Pow = 0.76. Temperature:22 °C.
Vapour pressure	202.6 Pa. Temperature:25 °C.
Density and/or relative density	0.98. Temperature:20 °C.
Relative vapour density	no data available
Particle characteristics	no data available

SECTION 10: Stability and reactivity

10.1Reactivity

On combustion, forms acetic acid fumes.

10.2Chemical stability

no data available

10.3Possibility of hazardous reactions

On combustion, forms acetic acid fumes.

10.4Conditions to avoid

no data available

10.5Incompatible materials

no data available

10.6Hazardous decomposition products

no data available

SECTION 11: Toxicological information

Acute toxicity

• Oral: LDLo - rat (male/female) - > 5 000 mg/kg bw.
• Inhalation: LC50 - rat (male/female) - > 6.99 mg/L air (analytical).
• Dermal: approximate LD50 - rabbit - 13.42 mL/kg bw.

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

no data available

Reproductive toxicity

no data available

STOT-single exposure

The substance is mildly irritating to the eyes.

STOT-repeated exposure

no data available

Aspiration hazard

No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C.

SECTION 12: Ecological information

12.1Toxicity

• Toxicity to fish: LC50 - Oncorhynchus mykiss (previous name: Salmo gairdneri) - 140 mg/L - 96 h.
• Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna - 110 mg/L - 48 h.
• Toxicity to algae: EC50 - Desmodesmus subspicatus (previous name: Scenedesmus subspicatus) - > 100 mg/L - 72 h.
• Toxicity to microorganisms: EC10 - Pseudomonas putida - 560 mg/L - 16 h.

12.2Persistence and degradability

no data available

12.3Bioaccumulative potential

no data available

12.4Mobility in soil

no data available

12.5Other adverse effects

no data available

SECTION 13: Disposal considerations

13.1Disposal methods

Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

SECTION 14: Transport information

14.1UN Number

ADR/RID: UN1993 (For reference only, please check.)

IMDG: UN1993 (For reference only, please check.)

IATA: UN1993 (For reference only, please check.)

14.2UN Proper Shipping Name

ADR/RID: FLAMMABLE LIQUID, N.O.S. (For reference only, please check.)

IMDG: FLAMMABLE LIQUID, N.O.S. (For reference only, please check.)

IATA: FLAMMABLE LIQUID, N.O.S. (For reference only, please check.)

14.3Transport hazard class(es)

ADR/RID: 3 (For reference only, please check.)

IMDG: 3 (For reference only, please check.)

IATA: 3 (For reference only, please check.)

14.4Packing group, if applicable

ADR/RID: I (For reference only, please check.)

IMDG: I (For reference only, please check.)

IATA: I (For reference only, please check.)

14.5Environmental hazards

ADR/RID: No

IMDG: No

IATA: No

14.6Special precautions for user

no data available

14.7Transport in bulk according to IMO instruments

no data available

SECTION 15: Regulatory information

15.1Safety, health and environmental regulations specific for the product in question

Chemical name	Common names and synonyms	CAS number	EC number
2-ethoxy-1-methylethyl acetate	2-ethoxy-1-methylethyl acetate	54839-24-6	259-370-9
European Inventory of Existing Commercial Chemical Substances (EINECS)			Listed.
EC Inventory			Listed.
United States Toxic Substances Control Act (TSCA) Inventory			Not Listed.
China Catalog of Hazardous chemicals 2015			Not Listed.
New Zealand Inventory of Chemicals (NZIoC)			Listed.
Philippines Inventory of Chemicals and Chemical Substances (PICCS)			Not Listed.
Vietnam National Chemical Inventory			Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC)			Listed.
Korea Existing Chemicals List (KECL)			Listed.

SECTION 16: Other information

Information on revision

Creation Date	July 15, 2019
Revision Date	July 15, 2019

Abbreviations and acronyms

• CAS: Chemical Abstracts Service
• ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
• RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
• IMDG: International Maritime Dangerous Goods
• IATA: International Air Transportation Association
• TWA: Time Weighted Average
• STEL: Short term exposure limit
• LC50: Lethal Concentration 50%
• LD50: Lethal Dose 50%
• EC50: Effective Concentration 50%

 

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